Posted by chemstudent on Tuesday, April 13, 2010 at 6:30pm.
I looked up
Fe^+2 ==> Fe^+3 + e. Loss of electrons is oxidation so Fe+2 is being oxidized; therefore it is the reducing agent.
Mn^+2 ==> Mn(IV) + 2e
Fe = -0.77
Mn = -1.24
Therefore, Fe is the more positive value so it's better.
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