Posted by Anonymous on Friday, April 2, 2010 at 4:40pm.
This is a confusing point and most text books get it right; however, they often fail to CLEARLY define which system they are discussing. Here is the correct skinny.
By definition, the anode is where oxidation occurs. That is the ONLY definition that counts. It is the ONLY one that is correct in all situations.
Having said all of that,
a) in batteries, the anode is the negative electrode.
b) in electrolysis cells (electroplating), the anode is the positive electrode.
In my classes, it is/was usual that students coming in to college chemistry thought that the anode was positive and the cathode was negative. In fact, I was taught that in grade school and high school. The fact is we were ALWAYS talking about electrolytic cells. In college the prof starts talking about the anode (and it was clearly marked negative) and I came unglued.
Ah, that makes a bit more sense. Thanks for clearing it up for me.
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