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March 26, 2017

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Starting with o.3700 mol CO (g) and 5.400*10^-2 COCl2 (g), in a 3 liter flask at 668 K, how many moles of Cl2 will be present?

CO + Cl2 =++COCL2

KC = 1.2*10^3 at 668 K

  • chemistry - ,

    How many moles of Cl2 will be present WHEN? Today? tomorrow? next week? perhaps you mean at equilibrium?
    CO + Cl2==> COCl2

    Set up an ICE chart.
    initial:
    CO = 0.37/3 = 0.123
    Cl2 = 0.054/3 = 0.018
    COCl2 = 0

    change:
    COCl2 = +x
    CO = -x
    Cl2 = -x

    equilibrium:
    CO = 0.123-x
    Cl2 = 0.018-x
    COCl2 = x

    Kc = (COCl2)^2/(CO)(Cl2)
    Substitute the equilibrium concns above into Ka expression and solve for x.

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