Posted by Anonymous on Sunday, January 24, 2010 at 5:07pm.
Add Cl^- (the common ion effect--just a practical example of Le Chatelier's Principle) puts the stress on the equilibrium, the reaction shifts to as to relieve the stress which means that the reaction must try to reduce the Cl^-. The only way it can do that is to shift to the left meaning that NaCl is LESS soluble in a solution with excess chloride in it.
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