Posted by Marrion on Friday, October 9, 2009 at 11:32pm.
I may have missed something on reading it but I agree that all should form at least some Na3PO4. And I don't see how (c) can be the correct answer.
The correct answer is (a) based on the first chemical equation below.
The mole ratio of NaOH to H3PO4 determines which salt is produced. Only the first one produces Na3PO4:
H3PO4 + 3NaOH ---> Na3PO4 + 3H2O
H3PO4 + 2NaOH ---> Na2HPO4 + 2H2O
H3PO4 + NaOH ---> NaH2PO4 + H2O
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