Hey i have a question regarding disproportionate reactions:

Permanganate ions MnO4 reacts with oxalic acid, H2C2O4 in acidic aqueous solution, producing manganese(II) ions and carbon dioxide. The skeletal equation is

MnO4^-(aq)+ H2C2O4(aq)--> Mn^2+(aq)+ Co2 (g)

balance this reaction in acidic solution

So first i write down the 2 half reactions, and balance them

MnO4^-(aq)+ 8H^+ --> Mn^2+(aq)+ 4H2O

and

H2C2O4(aq)+ 2H^+ --> Co2(g)+ 2H20

I know i have to determine the electron charges, this is where i am sure what to do, i am getting confused as to how to add up the electron charges on each side , i know that i have to to that in both the half reaction and cancel them out and get the net ionic equation...can someone please help me understand the electron charges part:

I think MnO4 is oxidizing here, and H2C2O4 is reducing

MnO4^-(aq)+ 8H^+ --> Mn^2+(aq)+ 4H2O

H2C2O4(aq)+ 2H^+ --> CO2(g)+ 2H20
There are two ways to do it.
1. Look at the total charge on the left for the first equation. It is -1+8 = +7 and on the right it is +2. So you must add 5 electrons to the left [+7+(-5)=+2] to make it balance. In others words, add electrons to the appropriate side to make the charges balance.

2. The other way is to look at the oxidation state of Mn on the left. It is +7. On the right Mn is +2. Going from +7 to +2 means it must have gained 5e so you add 5e to the left side. The nice part about either of these tracks is that they always work.

I forgot to mention that the H2C2O4 half equation is not balanced the way you have it.

To determine the electron charges in each half-reaction, you need to assign oxidation states to each element involved.

In the permanganate ion half-reaction:

MnO4^-(aq) + 8H^+ --> Mn^2+(aq) + 4H2O

The oxidation state of manganese (Mn) in MnO4^- is +7, and it becomes +2 in Mn^2+. This means that Mn has gained 5 electrons.

In the oxalic acid half-reaction:

H2C2O4(aq) + 2H^+ --> Co2(g) + 2H2O

Here, the carbon (C) in H2C2O4 has a oxidation state of +3 and becomes +4 in CO2. This means that carbon loses 1 electron.

To balance the electron charges in the overall reaction, you need to multiply each half-reaction by a suitable coefficient so that the total number of electrons gained in the oxidation half-reaction equals the total number of electrons lost in the reduction half-reaction.

In this case, since Mn gains 5 electrons and C loses 1 electron, you can multiply the oxalic acid half-reaction by 5 and the permanganate ion half-reaction by 1 to make the electron charges balance:

5(H2C2O4(aq) + 2H^+ --> CO2(g) + 2H2O)
1(MnO4^-(aq) + 8H^+ --> Mn^2+(aq) + 4H2O)

Now, add the two balanced half-reactions together:

5H2C2O4 + 10H^+ + MnO4^- + 8H^+ --> 5CO2 + 10H2O + Mn^2+ + 4H2O

Simplifying:

5H2C2O4 + 18H^+ + MnO4^- --> 5CO2 + Mn^2+ + 14H2O

This is the balanced net ionic equation for the reaction in acidic solution.

To balance the redox reaction in acidic solution, you need to ensure that the total charges and atoms are balanced in both half-reactions. Let's break down the process step by step:

1. Write the skeleton equation:
MnO4^-(aq) + H2C2O4(aq) -> Mn^2+(aq) + CO2 (g)

2. Identify the half-reactions:
Separate the reaction into two half-reactions, one for the oxidation and one for the reduction.

Oxidation half-reaction:
MnO4^-(aq) -> Mn^2+(aq)

Reduction half-reaction:
H2C2O4(aq) -> CO2 (g)

3. Balance the atoms:
Balance the number of atoms in each half-reaction, excluding oxygen and hydrogen.

Oxidation half-reaction:
MnO4^-(aq) -> Mn^2+(aq)

Reduction half-reaction:
H2C2O4(aq) -> 2 CO2 (g)

4. Balance the oxygen atoms:
Add water (H2O) to the side that needs oxygen atoms to balance.

Oxidation half-reaction:
MnO4^-(aq) -> Mn^2+(aq) + 4 H2O

Reduction half-reaction:
H2C2O4(aq) -> 2 CO2 (g) + 4 H2O

5. Balance the hydrogen atoms:
Add hydrogen ions (H^+) to balance the hydrogen atoms.

Oxidation half-reaction:
MnO4^-(aq) + 8 H^+ -> Mn^2+(aq) + 4 H2O

Reduction half-reaction:
H2C2O4(aq) + 2 H^+ -> 2 CO2 (g) + 4 H2O

6. Balance the charges:
Add electrons (e^-) to balance the charges on both sides. The number of electrons should be equal in both half-reactions.

Oxidation half-reaction:
MnO4^-(aq) + 8 H^+ + 5e^- -> Mn^2+(aq) + 4 H2O

Reduction half-reaction:
H2C2O4(aq) + 2 H^+ + 2e^- -> 2 CO2 (g) + 4 H2O

7. Cancel out electrons:
Multiply each half-reaction by integers to ensure that the number of electrons is the same in both reactions. In this case, you can multiply the reduction half-reaction by 5 and the oxidation half-reaction by 2 to make the number of electrons the same (10e^-).

Oxidation half-reaction:
2 MnO4^-(aq) + 16 H^+ + 10e^- -> 2 Mn^2+(aq) + 8 H2O

Reduction half-reaction:
5 H2C2O4(aq) + 10 H^+ + 10e^- -> 10 CO2 (g) + 20 H2O

8. Combine the two half-reactions:
Add the two balanced half-reactions together and simplify:

2 MnO4^-(aq) + 16 H^+ + 10e^- + 5 H2C2O4(aq) + 10 H^+ + 10e^- -> 2 Mn^2+(aq) + 8 H2O + 10 CO2 (g) + 20 H2O

Simplify the equation and cancel out the spectator ions:

2 MnO4^-(aq) + 5 H^+ + 5 H2C2O4(aq) -> 2 Mn^2+(aq) + 10 CO2 (g) + 18 H2O

So, the balanced net ionic equation in acidic solution is:

2 MnO4^-(aq) + 5 H^+ + 5 H2C2O4(aq) -> 2 Mn^2+(aq) + 10 CO2 (g) + 18 H2O