hey everyone out there im new to this forum so please be nice. hahaha :D as the subject says this is about ozone cracking. well my friend is doing a research assignment, and shes talking about ozone cracking. she has done your homework and found out that ozone cracking, actually cracks rubber but she needs an equation along with her work and she( nor i) can find an equation for this and i thought that maybe some people on some forums might so that's what i would like to know.

equation for ozone cracking, causing rubber to crack

Hi Anonymous,

Truthfully speaking I don't know much about ozone cracking. However, seeing that no one has answered your query for almost two hours, I will try to help.
The definition of ozone cracking as stated in Britannica Encyclopedia is as such:
"Atmospheric ozone reacts readily with elastomers containing C=C double bonds, leading to breakage of molecules lying in the surface."
Therefore, I would guess that ozone, o3, reacts with some unsaturated organic molecule, to remove one carbon or the bonds.
I'm really not sure and this is a speculation of mine. If I'm not wrong, this is quite similar to when chlorine in CFCs break up the ozone layer?
Hope I've helped you :)

I have been debating for two hours on how to answer. The question is silly. There will be no equations except for testing standards, then those equations will only involve the dimensions of the material to be tested. Rubber is not a material which lends itself to exactness, as equations often do.

The ozone layer is not cracking it is simply getting thinner nor is there a hole it is just getting thinner due to the CFC's and carbon dioxide

Hello and welcome to the forum! I'd be happy to help you and your friend with finding an equation for ozone cracking.

Ozone cracking, also known as environmental cracking or weather cracking, is a phenomenon where rubber materials degrade and develop cracks when exposed to ozone gas, which is present in the Earth's atmosphere. Ozone cracking is mainly observed in elastomers, such as natural rubber and synthetic rubber.

While there isn't a specific equation that describes ozone cracking, the process can be explained by several chemical reactions. Ozone reacts with unsaturated compounds in rubber, leading to the formation of oxidation products, and ultimately causing the rubber to crack.

The reaction between ozone and unsaturated compounds in rubber typically involves a type of double bond known as a carbon-carbon double bond:

C=C + O3 → O=C-O-C=C

This reaction produces an ozonide, which can decompose further and cause the formation of cracks in the rubber. The cracked rubber surface exposes fresh unsaturated bonds, thus facilitating more ozone attack and the continuation of the cracking process.

It's important to note that the extent of cracking depends on several factors, including the ozone concentration, exposure duration, temperature, and the type of rubber used. Additionally, the physical properties of the rubber, such as its molecular structure and cross-linking, also play a role in determining the susceptibility to ozone cracking.

Therefore, rather than a single equation, understanding the mechanisms and factors influencing ozone cracking is more important for studying and mitigating its effects.

I hope this explanation helps your friend with her research assignment! If you have any more questions, feel free to ask.