which molecule or compound below contains a polar covalent bond? why?

C2H4

LiI

NCL3

ZnS

AgCl

Out of the given molecules or compounds, the one that contains a polar covalent bond is NCl3 (nitrogen trichloride).

NCl3 contains a polar covalent bond because nitrogen (N) and chlorine (Cl) have different electronegativities. Chlorine is more electronegative than nitrogen, which means that it attracts the shared electrons in the covalent bond closer to its nucleus, creating a partial negative charge (δ-) on chlorine and a partial positive charge (δ+) on nitrogen. This uneven distribution of electron density across the bond results in a polar covalent bond in NCl3.

To determine which molecule or compound contains a polar covalent bond, we need to understand the concept of electronegativity. Electronegativity is a measure of an atom's ability to attract electrons towards itself in a chemical bond.

In a covalent bond, two atoms share electrons. If the two atoms have different electronegativities, the shared electrons will spend more time closer to the atom with higher electronegativity, resulting in a polar covalent bond.

Now, let's analyze each molecule or compound and determine whether they contain a polar covalent bond:

1. C2H4 (ethylene): Carbon (C) and hydrogen (H) have different electronegativities, but the electronegativity difference is relatively small. As a result, the C-H bonds in C2H4 are generally considered nonpolar.

2. LiI (lithium iodide): Although lithium (Li) and iodine (I) have different electronegativities, the electronegativity difference is significant. This difference causes the electron density to be more towards the iodine atom, resulting in a polar covalent bond in LiI.

3. NCl3 (nitrogen trichloride): Nitrogen (N) and chlorine (Cl) have different electronegativities. As a result, the N-Cl bonds in NCl3 are polar covalent.

4. ZnS (zinc sulfide): Zinc (Zn) and sulfur (S) have similar electronegativities, so the electron distribution between them is relatively even. Consequently, ZnS does not have polar covalent bonds.

5. AgCl (silver chloride): Silver (Ag) and chlorine (Cl) have significant electronegativity differences, causing the Cl-Ag bond to be polar covalent in AgCl.

In summary, the molecules LiI (lithium iodide), NCl3 (nitrogen trichloride), and AgCl (silver chloride) contain polar covalent bonds.

Draw the Lewis dot structure for each of the molecules. You can eliminate LiI, ZnS and AgCl because they are not covalent (but they are polar). The correct one, of the two remaining, is the one with an unshared pair of electrons.